Required Temperature (°C) For One Hour And Ten Hours Half-life
| Initiator |
T(°C) - 1 h |
T(°C) - 10 h |
|
2,3-Dimethyl-2,3-diphenylbutane |
247 |
224 |
|
tert-Butyl hydroperoxide |
193 |
169 |
|
tert-Amyl hydroperoxide |
190 |
153 |
|
Cumyl hydroperoxide |
166 |
140 |
|
1,1,3,3-Tetramethylbutyl hydroperoxide |
159 |
140 |
|
Isopropylcumyl hydroperoxide |
154 |
129 |
|
Isopropylcumyl hydroperoxide |
154 |
129 |
|
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 |
147 |
124 |
|
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane |
146 |
125 |
|
Di(tert-butyl)peroxide |
144 |
123 |
|
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane |
139 |
118 |
|
Di(tert-butylperoxy-isopropyl)benzene |
138 |
117 |
|
tert-Butyl cumyl peroxide |
137 |
117 |
|
Di-(tert-amyl)-peroxide |
135 |
113 |
|
Dicumyl peroxide |
135 |
114 |
|
Butyl 4,4-di(tert-butylperoxy)valerate |
125 |
102 |
|
tert-Butylperoxybenzoate |
124 |
104 |
|
2,2-Di(tert-butylperoxy)butane |
120 |
101 |
|
tert-Amyl peroxy-benzoate |
120 |
101 |
|
tert-Butylperoxy-acetate |
120 |
101 |
|
tert-Butylperoxy-(2-ethylhexyl)carbonate |
120 |
99 |
|
tert-Butylperoxy isopropyl carbonate |
117 |
98 |
|
tert-Butyl
peroxy-3,5,5-trimethyl-hexanoate |
117 |
97 |
|
1,1-Di(tert-butylperoxy)cyclohexane |
115 |
96 |
|
tert-Amyl peroxyacetate |
114 |
96 |
|
tert-Amylperoxy-(2-ethylhexyl)carbonate |
113 |
95 |
|
1,1-Di(tert-butylperoxy)-3,5,5-trimethylcyclohexane |
110 |
90 |
|
1,1-Di(tert-amylperoxy)cyclohexane |
106 |
87 |
|
tert-Butyl-monoperoxy-maleate |
104 |
82 |
|
1,1’-Azodi(hexahydrobenzonitrile) |
103 |
85 |
|
tert-Butyl peroxy-isobutyrate |
97 |
78 |
|
tert-Butyl peroxydiethylacetate |
93 |
75 |
|
tert-Butyl peroxy-2-ethylhexanoate |
92 |
73 |
|
Dibenzoyl peroxide |
91 |
72 |
|
tert-Amyl peroxy-2-ethylhexanoate |
91 |
73 |
|
Di(4-methylbenzoyl)peroxide |
89 |
70 |
|
1,1,3,3-Tetramethylbutyl
peroxy-2-ethylhexanoate |
88 |
69 |
|
Ammoniumperoxodisulfate |
87 |
69 |
|
2,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane |
85 |
68 |
|
2,2’-Azodi(2-methylbutyronitrile) |
84 |
66 |
|
2,2’-Azodi(isobutyronitrile) |
81 |
63 |
|
Didecanoyl peroxide |
80 |
63 |
|
Dilauroyl peroxide |
79 |
61 |
|
Di(3,5,5-trimethylhexanoyl) peroxide |
78 |
59 |
|
tert-Amyl peroxypivalate |
72 |
54 |
|
tert-Butyl peroxyneoheptanoate |
68 |
50 |
|
1,1,3,3-Tetramethylbutyl peroxypivalate |
66 |
48 |
|
tert-Butyl peroxypivalate |
75 |
57 |
|
Dicetyl peroxydicarbonate |
65 |
48 |
|
Dimyristyl peroxydicarbonate |
65 |
48 |
|
Di(2-ethylhexyl) peroxydicarbonate |
64 |
47 |
|
Di(4-tert-butylcyclohexyl)
peroxydicarbonate |
64 |
48 |
|
Diisopropyl peroxydicarbonate |
64 |
47 |
|
tert-Butyl peroxyneodecanoate |
64 |
47 |
|
Di-sec-butyl peroxydicarbonate |
63 |
47 |
|
tert-Amyl peroxyneodecanoate |
62 |
44 |
|
Cumyl peroxyneoheptanoate |
59 |
42 |
|
Di(3-methoxybutyl) peroxydicarbonate |
57 |
43 |
|
1,1,3,3-Tetramethylbutyl
peroxyneodecanoate |
57 |
40 |
|
Cumyl peroxyneodecanoate |
55 |
38 |
|
Diisobutyryl peroxide |
39 |
23 |