Poly(tetrafluoropropyl acrylate)

Poly(tetrafluoropropyl acrylate)

Poly(2,2,3,3-tetrafluoropropyl acrylate)

NAMES AND IDENTIFIERS OF POLYMER

POLYMER CLASS	Polyacrylate
COMMON NAMES	Poly(2,2,3,3-tetrafluoropropyl acrylate)
STRUCTURE BASED NAME	Poly(2,2,3,3-tetrafluoropropyl propenoate)
ACRONYMS
CAS #
CurlySMILES	C{-}C{n+}(C(=O)OCC(F)(F)C(F)F

IDENTIFIERS OF MONOMER(S)

CAS #	7383-71-3
COMMON NAMES	2,2,3,3-Tetrafluoropropyl acrylate
SMILES	FC(F)C(F)(F)COC(=O)C(=C)
Std. InChI	InInChI=1S/C6H6F4O2/c1-2-4(11)12-3-6(9,10)5(7)8/h2,5H,1,3H2
Std. InChIKey	VHJHZYSXJKREEE-UHFFFAOYSA-N
STRUCTURE

Thermo-Physical Properties: Experimental / Literature Data

PROPERTY	UNIT	VALUE / RANGE	PREFERRED
Molar Volume V_m	mL mol^-1	122.5
Density ρ	g mL^-1	1.52
Solubility Parameter δ	MPa^1/2
Molar Cohesive Energy E_coh	J mol^-1
Glass Transition Temperature T_g	K	247 - 251	249
Molar Heat Capacity C_p	J (mol K)^-1
Entanglement Molecular Weight M_e	g mol^-1
Index of Refraction n	none	1.42

Thermo-Physical Properties: Calculated Data

PROPERTY	UNIT	VALUE / RANGE	PREFERRED
Molecular Weight of Repeat unit	g mol^-1	186.1
Van-der-Waals Volume V_vW	mL mol^-1	74.0
Molar Volume V_m	mL mol^-1	115 - 122	119
Density ρ	g mL^-1	1.52 - 1.58	1.54
Solubility Parameter δ	MPa^1/2	16.0 - 16.9	16.5
Molar Cohesive Energy E_coh	J mol^-1	29700 - 33400	31500
Glass Transition Temperature T_g	K	232 - 268	250
Molar Heat Capacity C_p	J (mol K)^-1	260 - 285	270
Entanglement Molecular Weight M_e	g mol^-1	22900 - 26500	24700
Index of Refraction n	none	1.40 - 1.42	1.41

Last updated: October 25, 2015

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