Thermoplastic Polyamide Elastomers
Copolyamide Elastomers (COPAs)
Properties and Applications
Polyamide block copolymers
(COPAs) are high-performance, light-weight thermoplastic elastomers based on
polyester-amide (PEA), polyether-esteramide (PEEA), or polyether-amide
(PEBA) block
copolymers. The polyamide portion forms the hard (thermoplastic)
domains, while the polyester, polyether-ester or polyether blocks
form the soft elastomeric matrix.
COPAs offer one of the best combination
of performance and processability among thermoplastic elastomers.
They have a relative high service
temperature due to the strong hydrogen-bonding amide domains
which results in low creep, good heat aging, and improved solvent resistance. The
commercially most important polyamide elastomers are polyether-amide
block copolymers (PEBA). These elastomers possess
outstanding (low
temperature) flexibility and flex fatigue along with good resistance
to weathering, chemicals, wear and heat which are far better than those of
conventional rubber making these elastomer an excellent choice for applications
requiring high durability after cyclic loading at varying temperatures
and in various chemical environments.
For even more demanding applications, COPAs are often glass fiber or carbon fiber reinforced which improves strength and rigidity.
Like ordinary thermoplastics, COPAs can be easily processed on conventional high-volume plastic processing equipment including precission injection molding, blow molding, thermoforming, and extrusion equipment.
COPAs are widely used in the sport and leisure goods industry. Important applications include
outsoles, alpine ski boots, goggles, tennis rackets, bike handles and more. In the medical industry, thermoplastic polyamide
elastomers are used for medical devices requiring good flexibility, breathability, and sterilization resistance. COPAs are
also used in various household goods including handles for screwdrivers, kitchen tools and knifes.
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